| 1 |  Gert Steegmans (BEL) | Quick Step | 3.55.23 (37.624 km/h) |
| 2 |  Tomas Vaitkus (LTU) | Astana | mt |
| 3 |  Alejandro Valverde Belmonte (ESP) | Caisse d'Epargne | mt |
| 4 | Philippe Gilbert (BEL) | La Française des Jeux | 0.02 |
| 5 |  Sebastian Langeveld (P-B) | Rabobank | mt |
| 6 | Juan Antonio Flecha Giannoni (ESP) | Rabobank | mt |
| 7 | Alberto Losada Alguacil (ESP) | Caisse d'Epargne | mt |
| 8 | Bram Tankink (P-B) | Rabobank | mt |
| 9 | Manuel Ortega Ocana (ESP) | Andalucía - Cajasur | mt |
| 10 | Haimar Zubeldia Aguirre (ESP) | Euskaltel - Euskadi | mt |
| 11 | Ruben Perez Moreno (ESP) | Euskaltel - Euskadi | mt |
| 12 | Maarten Wynants (BEL) | Quick Step | mt |
| 13 | Aitor Perez Arrieta (ESP) | Extremadura - Grupo Gallardo | mt |
| 14 | Arkaitz Duran Aroca (ESP) | Saunier Duval - Scott | mt |
| 15 |  Giovanni Visconti (ITA) | Quick Step | mt |
| 16 |  Mickael Delage (FRA) | La Française des Jeux | mt |
| 17 | Manuele Mori (ITA) | Saunier Duval - Scott | 0.07 |
| 18 | Jon Bru Pascal (ESP) | Euskaltel - Euskadi | mt |
| 19 | David Herrero Llorente (ESP) | Karpin - Galicia | mt |
| 20 | Jesus Rosendo Prado (ESP) | Andalucía - Cajasur | mt |
| 21 | Francisco Perez Sanchez (ESP) | Caisse d'Epargne | mt |
| 22 | Iban Mayoz Etxebarria (ESP) | Karpin - Galicia | mt |
| 23 |  Grégory Rast (SUI) | Astana | mt |
| 24 | David De La Fuente Rasilla (ESP) | Saunier Duval - Scott | mt |
| 25 | Antonio Colom Mas (ESP) | Astana | mt |
| 26 | Ezequiel Mosquera Miguez (ESP) | Karpin - Galicia | mt |
| 27 |  Eduard Vorganov (RUS) | Karpin - Galicia | mt |
| 28 | Gorka Verdugo Marcotegui (ESP) | Euskaltel - Euskadi | mt |
| 29 | Jose Ruiz Sanchez (ESP) | Andalucía - Cajasur | mt |
| 30 | Matteo Carrara (ITA) | Quick Step | mt |
| 31 |  Markus Fothen (ALL) | Gerolsteiner | mt |
| 32 | Luis Pasamontes Rodriguez (ESP) | Caisse d'Epargne | mt |
| 33 | Tristan Valentin (FRA) | Cofidis | mt |
| 34 | Sébastien Minard (FRA) | Cofidis | mt |
| 35 | Grischa Niermann (ALL) | Rabobank | mt |
| 36 | Rafael Valls Ferri (ESP) | Saunier Duval - Scott | 0.13 |
| 37 | Johnny Hoogerland (P-B) | Van Vliet - Ebh - Elshof | mt |
| 38 | Oscar Pujol Muñoz (ESP) | Burgos Monumental | mt |
| 39 | Francisco Javier Aramendia Llorente (ESP) | Euskaltel - Euskadi | 0.15 |
| 40 | Steve Morabito (SUI) | Astana | mt |
| 41 | Jose Luis Carrasco Gamiz (ESP) | Andalucía - Cajasur | mt |
| 42 | Javier Moreno Bazan (ESP) | Andalucía - Cajasur | mt |
| 43 | José Ángel Gómez Marchante (ESP) | Saunier Duval - Scott | mt |
| 44 | Inigo Landaluze Intxaurraga (ESP) | Euskaltel - Euskadi | mt |
| 45 | Joan Llaneras Rosello (ESP) | Burgos Monumental | mt |
| 46 | Iban Velasco Murillo (ESP) | Euskaltel - Euskadi | mt |
| 47 | Stijn Devolder (BEL) | Quick Step | mt |
| 48 | Hubert Schwab (SUI) | Quick Step | mt |
| 49 | Nick Nuyens (BEL) | Cofidis | mt |
| 50 | Alberto Fernandez Sainz (ESP) | Karpin - Galicia | mt |
| 51 | Pablo Lastras Garcia (ESP) | Caisse d'Epargne | mt |
| 52 | Stephan Schreck (ALL) | Gerolsteiner | mt |
| 53 | Sergio Pardilla Bellón (ESP) | Burgos Monumental | mt |
| 54 | David Arroyo Duran (ESP) | Caisse d'Epargne | mt |
| 55 | Tom Stamsnijder (P-B) | Gerolsteiner | mt |
| 56 |  Benoît Joachim (LUX) | Astana | mt |
| 57 | Kevin De Weert (BEL) | Cofidis | mt |
| 58 | Lander Aperribai Aranda (ESP) | Euskaltel - Euskadi | 0.20 |
| 59 | Gonzalo Rabunal Rios (ESP) | Karpin - Galicia | 0.22 |
| 60 | Joaquim Rodríguez Oliver (ESP) | Caisse d'Epargne | mt |
| 61 | David Lopez Garcia (ESP) | Caisse d'Epargne | mt |
| 62 | Jelle Vanendert (BEL) | La Française des Jeux | mt |
| 63 | Beñat Intxausti Elorriaga (ESP) | Saunier Duval - Scott | mt |
| 64 | Sandy Casar (FRA) | La Française des Jeux | mt |
| 65 |  Martin Mares (RTC) | PSK Whirlpool - Author | 0.25 |
| 66 | Rik Verbrugghe (BEL) | Cofidis | mt |
| 67 | Albert Timmer (P-B) | Skil - Shimano | 1.44 |
| 68 | Alberto Fernandez Sainz (ESP) | Karpin - Galicia | 2.51 |
| 69 | Joost Van Leijen (P-B) | Van Vliet - Ebh - Elshof | 5.19 |
| 70 | Delio Fernandez Cruz (ESP) | Karpin - Galicia | mt |
| 71 | Floris Goesinnen (P-B) | Skil - Shimano | 10.36 |
| 72 | Leonardo Scarselli (ITA) | Quick Step | mt |
| 73 | Addy Engels (P-B) | Quick Step | mt |
| 74 |  Marc De Maar (ANT) | Rabobank | mt |
| 75 | Francisco José Terciado Sacedo (ESP) | Extremadura - Grupo Gallardo | mt |
| 76 | Juan Manuel Gárate Cepa (ESP) | Quick Step | mt |
| 77 |  Graeme Allen Brown (AUS) | Rabobank | 15.49 |
| 78 | Bram Schmitz (P-B) | Van Vliet - Ebh - Elshof | mt |
| 79 | Jakub Danacik (RTC) | PSK Whirlpool - Author | mt |
| 80 | Yoann Offredo (FRA) | La Française des Jeux | mt |
| 81 | Emmanuel Van Ruitenbeek (P-B) | Van Vliet - Ebh - Elshof | mt |
| 82 | Maarten Den Bakker (P-B) | Skil - Shimano | mt |
| 83 | Koen De Kort (P-B) | Astana | mt |
| 84 | Ruben Martinez Hernandez (ESP) | Burgos Monumental | mt |
| 85 | Pedro Merino Criado (ESP) | Burgos Monumental | mt |
| 86 | Martin Mata Cabello (ESP) | Burgos Monumental | mt |
| 87 | Sebastian Lang (ALL) | Gerolsteiner | mt |
| 88 |  René Haselbacher (AUT) | Astana | mt |
| 89 | Mathieu Heijboer (P-B) | Cofidis | mt |
| 90 | Gonzalo Zambrano Calderon (ESP) | Extremadura - Grupo Gallardo | mt |
| 91 | José Vicente Garcia Acosta (ESP) | Caisse d'Epargne | mt |
| 92 | Arnaud Coyot (FRA) | Caisse d'Epargne | mt |
| 93 | José Antonio Redondo Ramos (ESP) | Andalucía - Cajasur | mt |
| 94 | Ruben Lobato Elvira (ESP) | Saunier Duval - Scott | mt |
| 95 | Tom Veelers (P-B) | Skil - Shimano | 19.57 |
| 96 | Frantisek Kloucek (RTC) | PSK Whirlpool - Author | mt |
| 97 |  Timothy Gudsell (NZL) | La Française des Jeux | mt |
| 98 | Stanislav Kozubek (RTC) | PSK Whirlpool - Author | mt |
| 99 |  Fumiyuki Beppu (JPN) | Skil - Shimano | mt |
| 100 | Radek Becka (RTC) | PSK Whirlpool - Author | mt |
| 101 | Roy Curvers (P-B) | Skil - Shimano | mt |
| 102 | Staf Scheirlinckx (BEL) | Cofidis | mt |
| 103 |  Frank Høj (DAN) | Cofidis | mt |
| 104 | Tomás Buchácek (RTC) | PSK Whirlpool - Author | mt |
| 105 | Patrick Keller (ALL) | PSK Whirlpool - Author | mt |
| 106 | Jarno Gmelich Meijling (P-B) | Van Vliet - Ebh - Elshof | mt |
| 107 | Francisco Javier Iriarte Garro (ESP) | Burgos Monumental | mt |
| 108 | Juan Olmo Menacho (ESP) | Andalucía - Cajasur | mt |
| 109 | José Vicente Toribio Alcolea (ESP) | Burgos Monumental | mt |
| 110 | Raul Santamarta Valvuena (ESP) | Burgos Monumental | mt |
| 111 | Sven Krauss (ALL) | Gerolsteiner | mt |
| 112 | Jesus Ramirez Torres (ESP) | Extremadura - Grupo Gallardo | mt |
| 113 | Xabat Ochotorena Arraras (ESP) | Extremadura - Grupo Gallardo | mt |
| 114 |  Ignacio Sarabia Diaz (MEX) | Extremadura - Grupo Gallardo | km 6.10 |
