| 1 |  José Joaquin Rojas Gil (ESP) | Caisse d'Epargne | 4.00.59 (41.928 km/h) |
| 2 |  Giovanni Visconti (ITA) | Quick Step | mt |
| 3 |  Philippe Gilbert (BEL) | La Française des Jeux | mt |
| 4 |  Sebastian Langeveld (P-B) | Rabobank | mt |
| 5 | Aitor Perez Arrieta (ESP) | Extremadura - Grupo Gallardo | mt |
| 6 | Manuele Mori (ITA) | Saunier Duval - Scott | mt |
| 7 | Benat Albizuri Aransono (ESP) | Euskaltel - Euskadi | mt |
| 8 | David Herrero Llorente (ESP) | Karpin - Galicia | mt |
| 9 | Gerben Löwik (P-B) | Rabobank | mt |
| 10 | Stijn Devolder (BEL) | Quick Step | mt |
| 11 |  Stephan Schreck (ALL) | Gerolsteiner | mt |
| 12 | Antonio Colom Mas (ESP) | Astana | mt |
| 13 | Haimar Zubeldia Aguirre (ESP) | Euskaltel - Euskadi | mt |
| 14 | Oscar Pujol Muñoz (ESP) | Burgos Monumental | mt |
| 15 | Jon Bru Pascal (ESP) | Euskaltel - Euskadi | mt |
| 16 | Jesus Rosendo Prado (ESP) | Andalucía - Cajasur | mt |
| 17 | Bram Tankink (P-B) | Rabobank | mt |
| 18 | Alberto Losada Alguacil (ESP) | Caisse d'Epargne | mt |
| 19 | Arkaitz Duran Aroca (ESP) | Saunier Duval - Scott | mt |
| 20 | David De La Fuente Rasilla (ESP) | Saunier Duval - Scott | mt |
| 21 | Ezequiel Mosquera Miguez (ESP) | Karpin - Galicia | mt |
| 22 | Manuel Ortega Ocana (ESP) | Andalucía - Cajasur | mt |
| 23 | Matteo Carrara (ITA) | Quick Step | mt |
| 24 | José Ángel Gómez Marchante (ESP) | Saunier Duval - Scott | mt |
| 25 | Iban Mayoz Etxebarria (ESP) | Karpin - Galicia | mt |
| 26 | Kevin De Weert (BEL) | Cofidis | mt |
| 27 | Matthias Russ (ALL) | Gerolsteiner | mt |
| 28 | Gorka Verdugo Marcotegui (ESP) | Euskaltel - Euskadi | mt |
| 29 | Francisco Javier Aramendia Llorente (ESP) | Euskaltel - Euskadi | mt |
| 30 | Juan Olmo Menacho (ESP) | Andalucía - Cajasur | mt |
| 31 |  Benoît Joachim (LUX) | Astana | mt |
| 32 | Javier Moreno Bazan (ESP) | Andalucía - Cajasur | mt |
| 33 |  Ignacio Sarabia Diaz (MEX) | Extremadura - Grupo Gallardo | mt |
| 34 | Jose Luis Carrasco Gamiz (ESP) | Andalucía - Cajasur | mt |
| 35 | Francisco Perez Sanchez (ESP) | Caisse d'Epargne | mt |
| 36 |  Tristan Valentin (FRA) | Cofidis | mt |
| 37 | Serafín Martínez Acevedo (ESP) | Karpin - Galicia | mt |
| 38 | Ruben Perez Moreno (ESP) | Euskaltel - Euskadi | mt |
| 39 | Koos Moerenhout (P-B) | Rabobank | mt |
| 40 | Alberto Fernandez Sainz (ESP) | Karpin - Galicia | mt |
| 41 | Addy Engels (P-B) | Quick Step | mt |
| 42 | Grischa Niermann (ALL) | Rabobank | mt |
| 43 |  Jakub Danacik (RTC) | PSK Whirlpool - Author | mt |
| 44 |  Vladimir Karpets (RUS) | Caisse d'Epargne | mt |
| 45 | David Arroyo Duran (ESP) | Caisse d'Epargne | mt |
| 46 | Christophe Mengin (FRA) | La Française des Jeux | mt |
| 47 |  Marc De Maar (ANT) | Rabobank | mt |
| 48 | Inigo Landaluze Intxaurraga (ESP) | Euskaltel - Euskadi | mt |
| 49 | Alessandro Proni (ITA) | Quick Step | mt |
| 50 | Beñat Intxausti Elorriaga (ESP) | Saunier Duval - Scott | mt |
| 51 |  Hubert Schwab (SUI) | Quick Step | mt |
| 52 | David Lopez Garcia (ESP) | Caisse d'Epargne | mt |
| 53 | Sergio Pardilla Bellón (ESP) | Burgos Monumental | mt |
| 54 | Rafael Valls Ferri (ESP) | Saunier Duval - Scott | mt |
| 55 | Alejandro Valverde Belmonte (ESP) | Caisse d'Epargne | 0.15 |
| 56 | Iban Velasco Murillo (ESP) | Euskaltel - Euskadi | 0.26 |
| 57 | Joaquim Rodríguez Oliver (ESP) | Caisse d'Epargne | 1.18 |
| 58 | Mathieu Heijboer (P-B) | Cofidis | 11.57 |
| 59 | Nick Nuyens (BEL) | Cofidis | mt |
| 60 | Staf Scheirlinckx (BEL) | Cofidis | mt |
| 61 | Salvador Guardiola Tora (ESP) | Seleccion Española | mt |
| 62 | Thomas Frei (SUI) | Astana | mt |
| 63 | Yoann Offredo (FRA) | La Française des Jeux | mt |
| 64 | Sandy Casar (FRA) | La Française des Jeux | mt |
| 65 | Ronny Scholz (ALL) | Gerolsteiner | mt |
| 66 |  Fumiyuki Beppu (JPN) | Skil - Shimano | mt |
| 67 | Maarten Den Bakker (P-B) | Skil - Shimano | mt |
| 68 | Claudio José Casas Gallego (ESP) | Andalucía - Cajasur | mt |
| 69 | José Vicente Toribio Alcolea (ESP) | Burgos Monumental | mt |
| 70 | Mickael Delage (FRA) | La Française des Jeux | mt |
| 71 | Pedro Gutierrez Alvarez (ESP) | Burgos Monumental | mt |
| 72 | Pablo Lastras Garcia (ESP) | Caisse d'Epargne | mt |
| 73 | Thierry Hupond (FRA) | Skil - Shimano | mt |
| 74 | Lars Vierbergen (P-B) | Van Vliet - Ebh - Elshof | mt |
| 75 | David Francisco Delgado (ESP) | Burgos Monumental | mt |
| 76 | Josu Mondelo Diaz (ESP) | Extremadura - Grupo Gallardo | mt |
| 77 | Benjamin Noval Gonzalez (ESP) | Astana | mt |
| 78 | Albert Timmer (P-B) | Skil - Shimano | mt |
| 79 | Rick Flens (P-B) | Rabobank | mt |
| 80 | Gonzalo Rabunal Rios (ESP) | Karpin - Galicia | mt |
| 81 | Delio Fernandez Cruz (ESP) | Karpin - Galicia | mt |
| 82 | Volker Ordowski (ALL) | Gerolsteiner | mt |
| 83 | Sébastien Minard (FRA) | Cofidis | mt |
| 84 | Eduard Vorganov (RUS) | Karpin - Galicia | mt |
| 85 | Julien Mazet (FRA) | Astana | mt |
| 86 | Carlos Castaño Panadero (ESP) | Karpin - Galicia | mt |
| 87 | Lander Aperribai Aranda (ESP) | Euskaltel - Euskadi | mt |
| 88 | Josu Agirre Aseginolaza (ESP) | Euskaltel - Euskadi | mt |
| 89 | Juan Manuel Gárate Cepa (ESP) | Quick Step | mt |
| 90 | Mauro Facci (ITA) | Quick Step | mt |
| 91 | Markus Fothen (ALL) | Gerolsteiner | mt |
| 92 | Jaume Rovira Pous (ESP) | Extremadura - Grupo Gallardo | mt |
| 93 | Dmitry Kozontchuk (RUS) | Rabobank | mt |
| 94 | Martin Mares (RTC) | PSK Whirlpool - Author | mt |
| 95 | Leopold König (RTC) | PSK Whirlpool - Author | mt |
| 96 | Steve Morabito (SUI) | Astana | mt |
| 97 | José Vicente Garcia Acosta (ESP) | Caisse d'Epargne | mt |
| 98 | Joost Van Leijen (P-B) | Van Vliet - Ebh - Elshof | mt |
| 99 | Johnny Hoogerland (P-B) | Van Vliet - Ebh - Elshof | mt |
| 100 |  Tomas Vaitkus (LTU) | Astana | 23.20 |
| 101 |  René Haselbacher (AUT) | Astana | mt |
| 102 |  Timothy Gudsell (NZL) | La Française des Jeux | mt |
| 103 | Jeffrey Wiersma (P-B) | Van Vliet - Ebh - Elshof | mt |
| 104 | Francisco Javier Iriarte Garro (ESP) | Burgos Monumental | mt |
| 105 | Roy Curvers (P-B) | Skil - Shimano | mt |
| 106 |  Frank Høj (DAN) | Cofidis | mt |
| 107 | Michiel Elijzen (P-B) | Rabobank | mt |
| 108 | Rik Verbrugghe (BEL) | Cofidis | mt |
| 109 | Clément Lhotellerie (FRA) | Skil - Shimano | mt |
| 110 | Piet Rooijakkers (P-B) | Skil - Shimano | mt |
| 111 | Diego Gallego Arnaiz (ESP) | Burgos Monumental | mt |
| 112 | Francisco José Terciado Sacedo (ESP) | Extremadura - Grupo Gallardo | mt |
| 113 | Emmanuel Van Ruitenbeek (P-B) | Van Vliet - Ebh - Elshof | mt |
| 114 | Thomas Fothen (ALL) | Gerolsteiner | mt |
| 115 | Robert Förster (ALL) | Gerolsteiner | mt |
| 116 | Gonzalo Zambrano Calderon (ESP) | Extremadura - Grupo Gallardo | mt |
| 117 | Juan Javier Estrada Ruiz (ESP) | Andalucía - Cajasur | mt |
| 118 | Rikke Dijkxhoorn (P-B) | Van Vliet - Ebh - Elshof | mt |
| 119 | Martin Mata Cabello (ESP) | Burgos Monumental | mt |
| 120 | Jesus Cobelo Fojo (ESP) | Karpin - Galicia | mt |
| 121 | Gert Steegmans (BEL) | Quick Step | mt |
| 122 | Koen De Kort (P-B) | Astana | mt |
| 123 | Israel Perez Rodriguez (ESP) | Extremadura - Grupo Gallardo | mt |
| 124 | Jesus Ramirez Torres (ESP) | Extremadura - Grupo Gallardo | mt |
| 125 | Frantisek Kloucek (RTC) | PSK Whirlpool - Author | 41.24 |
| 126 | Radek Becka (RTC) | PSK Whirlpool - Author | mt |
| 127 | Vojtech Dlouhy (RTC) | PSK Whirlpool - Author | mt |
| 128 | Fabien Bacquet (FRA) | Skil - Shimano | km. 26 |
